Alkali metals are all around us. The host says sodium probably powers the streetlights on your block, and lithium is a critical element in several kinds of long-lasting batteries. Storing and transporting them is therefore important, but putting them in a box is more complicated than it sounds.
Pure alkali metals cannot be exposed to oxygen. The host says oxygen is corrosive, and over enough time it completely converts pure sodium into sodium peroxide, leaving a different substance in the box than the one that was put in.
Water is not a solution either. Alkali metals are extremely electropositive, meaning they easily give up an electron. When they do, the electron bonds with water and releases energy, sometimes a great deal of it.
Instead, alkali metals can be kept in mineral oil, whose carbon and hydrogen atoms have similar electronegativities and bond with each other rather than pulling in other elements. They can also be surrounded by argon, a noble gas that already has all the electrons it needs and hardly reacts with anything. Lithium metal batteries are sealed in airtight containers, but the host warns that if the container is punctured they can catch fire or explode, which is why they should not be thrown in the trash.